{N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate
نویسندگان
چکیده
The title mononuclear complex, [Cu(C(18)H(12)N(2)O(2))(C(12)H(8)N(2))]·CH(3)OH, contains one N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand (L(2-)), a Cu(2+) cation, one 1,10-phenanthroline ligand and a methanol solvent mol-ecule. The Cu(II) ion adopts a CuO(2)N(3) distorted square-pyramidal coordination. An O-H⋯O hydrogen bond is formed between the methanol solvent mol-ecule and the hydrazide O atom of the L(2-) ligand.
منابع مشابه
{4-Amino-N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidato}dimethyltin(IV)
In the title compound, [Sn(CH3)2(C18H13N3O2)], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 4-amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate(2-) ligand and two C atoms from methyl ligands in a distorted trigonal-bipyramidal geometry. The dihedral angle between the naphthalene ring system and the benzene ring is 19.2 (2)°. In the crystal, weak N-H⋯O...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012